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INTRODUCTION
What is a solid waste? Put simply, a solid waste is any solid, semisolid,
liquid, or contained gaseous material that is discarded (i.e. not immediately
recaptured for reuse onsite). Obviously something that is thrown into a dumpster
is a solid waste. However, material that is dumped onto the ground, abandoned,
stored, accumulated, or treated in lieu of being disposed of is also a solid
waste.
HOW CAN I DETERMINE IF I HAVE A HAZARDOUS WASTE
Once a waste has been determined to be a solid waste, it must then be checked
to see if it is a hazardous waste. Tools that can be used include product
labels, Material Safety Data Sheets (MSDSs) and lab test results.
Even if the waste is not on one of the EPA lists (a listed waste - see
Step 1 below),
that waste must still be checked to see if it exhibits one of the four
characteristics of hazardous wastes (a characteristic waste - see
Step 2 below).
STEP 1: IS THE WASTE A LISTED WASTE
A solid waste is a hazardous waste if it is listed
as such on any of the three EPA hazardous waste lists located in 40 CRF 261
Subpart D (F, K, P, & U listed wastes)
- Specific Sources –
K001 to
K148: These are hazardous
wastes produced by a particular industrial activity.
Examples:
K016 distillation residue from carbon tetrachloride production, K061 emission
control dust.
- Nonspecific Sources
– F001 to
F039 – These are
generic hazardous wastes produced by general industry, manufacturing, &
maintenance operations.
Spent halogenated solvents used in degreasing - > 10%
concentrations of any of the following (before use): Tetrachloroethylene;
trichloroethylene; methylene chloride; 1,1,1-trichlorethane; carbon
tetrachloride; chlorinated fluorocarbons.
Examples: solvent degreasers, vapor degreasers.
Spent halogenated solvents - >10% concentration of any of the
following (before use): tetrachloroethylene; trichloroethylene; methylene
chloride; 1,1,1-trichloroethane; 1,1,2-trichloro-1; chlorobenzene;
1,2,2-trifluoroethane; ortho-dichlorobenzene; trichlorofluoromethane; 1,1,2-trichloroethane.
Examples: dry cleaning solvents (perc) , brake cleaners (perc,
trichloroehylene)
Spent Non-halogenated solvents - xylene; acetone; ethyl
acetate; ethyl benzene; ethyl ether; methyl isobutyl ketone; n-butyl alcohol;
cyclohexane; methanol.
Examples: acetone, paint thinners, xylene.
F004: Spent Non-halogenated solvents: >10% concentration of any
of the following (before use): cresols; cresylic acid; nitrobenzene.
Examples: Carburetor dip cleaner (cresylic acid).
Spent Non-halogenated solvents: >10% concentration of any of
the following (before use): toluene; methyl ethyl ketone; carbon disulfide;
isobutanol; pyridine; benzene; 2-ethoxyethanol; 2-nitropropane.
Examples: Lacquer thinners, (toluene,
methyl ethyl ketone).
Other wastes.
Examples: F006
electroplating sludge, F035 preservativedrainage from wood preserving.
- Commercial Chemical Products that have not been used but have become
wastes
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to U249 toxic material - Examples:
U002 acetone, U165 naphthalene, U220 toluene, U239 xylene.
to P122 wastes are very toxic and small amounts (1 Kg or
less per month) make a facility qualify for Large Quantity Generator
status.
Examples: P042 epinephrine, P075 nicotine, P089
parathion, P108 strychnine, some pharmaceutical wastes, some chemotherapy
wastes.
Note: A non-listed waste or a non-hazardous waste that comes
into contact with a listed waste becomes a listed waste.
Examples:
solvent contaminated cleaning rags, still bottoms, kitty litter used to clean
up a spill, contaminated soil or debris.
STEP 2: IS THE WASTE A CHARACTERISTIC WASTE?
Even if the waste is not on one of the EPA lists
(a listed waste),
that waste must still be checked to see if it exhibits one of the four
characteristics of hazardous wastes (a characteristic waste):
- Ignitable
– D001 - A liquid with a flash point less than 140°F.
Examples: liquids that contain >24% alcohol, oil based paints, mineral spirits, fuels.
- Corrosivity
– D002 - A liquid that has a pH of less than or
equal to 2; or greater than or equal to12.5. Examples: muriatic acid, sulfuric acid,
solutions of sodium hydroxide.
- Reactivity
– D003 - A waste is very unstable and readily
undergoes violent change without detonating, reacts violently, forms a potentially explosive mixture, or
generates a toxic gas when mixed with water.
Examples:
fireworks, gunpowder.
- Toxicity
– D004 to D043 - The extracts from a
representative sample are tested and are found to contain certain contaminates in greater concentrations than
permissible as listed in Table 1 of 40 CFR 261.
Examples:
paints containing heavy metals, sand blast grit, thermometers.
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Highlights
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